Measurement of Temperature

Temperature is measured by thermometer on physical properties that change linearly with temperature to give temperature readings. Physical properties of a thermometer include;

i)        Expansion of liquid (mercury or alcohol) when heated

ii)       Expansion of a compound strip of two metals

iii)     Thermoelectric property change in which when junction of two different metals are heated an electric current is generated

iv)     Change of resistance of a wire e.g. platinum resistance thermometer

NB:

i)        The liquid used in thermometer is called thermometric liquid

ii)       Temperature of the body is measured in degree centigrade, °C

 

Thermometric Scales

There are two scales of thermometer include;

i)        Celsius or Centigrade Scale

ii)       Fahrenheit Scale

Celsius or Centigrade Scale

This scale has 100 divisions between the upper and lower standard points. This scale was introduced by a Swedish Astronomer Celsius and is known after his name. Each division on this scale is called one degree centigrade or one degree Celsius and is written as 1°C.

More sensitive thermometers have 200 divisions between standard points and each division is equal to 1/2 °C. Sometimes these thermometers are called half °C thermometers.

Fahrenheit Scale

This scale was introduced by Fahrenheit. On this scale 32°F represents the melting point of ice and 212°F the steam point. Zero is marked 32°F below the ice point. The length in between the standard points is divided to 180 equal parts. Each division on this scale is called 1°F. This scale is widely used for meteorological and clinical purposes.

 

Diagram show the thermometric scale

Types of Thermometer

i)        Mercury in glass thermometer

ii)       Alcohol in glass thermometer

iii)     maximum and minimum thermometer

iv)     thermocouple thermometer

v)       Thermistor thermometer

 

Liquid in Glass Thermometer

The working of this kind of thermometer is contraction and expansion of the liquid inside the thermometer. Always mercury and alcohol used as liquid inside thermometer so we have two types of liquid in glass thermometer

i)        Mercury in glass thermometer

ii)       Alcohol in glass thermometer

Choice of Thermometric Liquid

A thermometric liquid must have the following properties

i)        It should have low specific heat capacity, so that it rapidly attains the temperature of a given substance, without absorbing any appreciable amount of heat energy from it.

ii)       It should have a uniform rate of expansion, such that a linear scale can be easy marked.

iii)     It should have large expansion for a unit degree rise in temperature, so that its expansion is visible to the unaided eye.

iv)     It should have a high boiling point and low freezing point, so that a wide range of temperature changes could be recorded by a single thermometer.

v)       It should be shiny and opaque so that it is clearly visible in glass.

vi)     It should not stick to the sides of the glass tube.

vii)   It should exert low vapour pressure.

viii)  It should be a good conductor of heat.

ix)     It should be easily available in pure state.

Why Mercury Used in Thermometer

i)        It has low specific heat capacity.

ii)       Its expansion is uniform.

iii)     It has a high boiling point (357°C) and low melting point (-39°C).

iv)     It is opaque and shining.

v)       It does not stick to the sides of the glass.

vi)     It exerts very low vapour pressure.

vii)   It is a good conductor of heat.

viii)  It is easily available in pure state.

Disadvantages of Mercury as Thermometric Liquid

i)        Its expansion is not very large for 1°C rise in temperature and hence, very small changes in temperature cannot be measured.

ii)       It freezes below -39°C and hence, it cannot be used in very cold regions like Antarctic or Arctic.

Why Alcohol Used in Thermometer

i)        Its freezing point is below -100°C and hence, can record very low temperatures.

ii)       Its expansion per degree centigrade rise in temperature is very large and hence, very sensitive thermometers can be made with it.

iii)     It can be coloured brightly and hence is easily visible.

Disadvantages of Alcohol as Thermometric Liquid

i)        It cannot be used for measuring high temperatures as alcohol boils at 78°C.

ii)       It has high specific heat capacity.

iii)     It sticks to the sides of glass.

iv)     It has a high vapour pressure.

v)       It is not a good conductor of heat.

vi)     It is difficult to obtain pure alcohol.

Disadvantages of Water as Thermometric Liquid

i)        It has the highest specific heat capacity (4.2 J/gK).

ii)       Its expansion is not uniform.

iii)     Its expansion per degree rise in temperature is very small

iv)     Its melting point is 0°C and boiling point 100°C. Thus, the temperatures less than 0°C and more than 100°C cannot t measured.

v)       It is transparent/colourless

vi)     It sticks to the sides of glass.

vii)   It evaporates under vacuum conditions.

viii)  It is a bad conductor of heat.

ix)     It cannot be obtained in cent per cent pure form easily.

Thermometer Fundamental Interval

Fundamental interval of a thermometer is the different between the upper fixed point and the lower fixed point of the thermometer.

Example, the upper fixed point of water is 100 °C and the lower fixed point of water is 0 °C

Types of Thermometer

vi)     Mercury in glass thermometer

vii)   Alcohol in glass thermometer

viii)  maximum and minimum thermometer

ix)     thermocouple thermometer

x)       Thermistor thermometer 

Liquid in Glass Thermometer

The working of this kind of thermometer is contraction and expansion of the liquid inside the thermometer. Always mercury and alcohol used as liquid inside thermometer so we have two types of liquid in glass thermometer

iii)     Mercury in glass thermometer

iv)     Alcohol in glass thermometer

 

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